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Updated: Jun 24, 2025

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
Published on: November 9, 2019
A novel porphyrin MOF catalyst for efficient conversion of CO2 with propargyl amines
Zhitao Zhang1, Kesheng Shen1, Qian Zhang1
1Add State Key Laboratory of Fine Chemicals, College of Chemistry, Dalian University of Technology, 116024, P. R. China. xjing@dlut.edu.cn.
Abstract:
The capture and conversion of carbon dioxide (CO2) into valuable chemical products under mild conditions is an important and challenging approach for contemporary industry. Carboxylic acid ligands are widely used in the development of functionalized metal organic framework materials due to their excellent stability. Herein, a novel mixed-metal organic framework Cu-TCPP(Fe) was assembled from iron-(Fe)-porphyrin ligands, which can efficiently catalyze the reaction of propargylic amines and CO2 to synthesize 2-oxazolidinones.
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