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Updated: Jun 24, 2025

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing
Published on: March 22, 2019
Comb-Referenced Doppler-Free Spectrometry of the ^{200}Hg and ^{202}Hg Intercombination Line at 254 nm
Stefania Gravina1, Naveed A Chishti1, Simona Di Bernardo1
1Dipartimento di Matematica e Fisica, Università degli Studi della Campania "Luigi Vanvitelli", 81100 Caserta, Italy.
Abstract:
We report on precision spectroscopy of the 6s^{2} ^{1}S_{0}→6s6p ^{3}P_{1} intercombination line of mercury in the deep ultraviolet, by means of a frequency-comb referenced, wavelength-modulated, saturated absorption technique. This method allowed us to perform sub-Doppler investigations with an absolute frequency axis at 254 nm, while ensuring a relatively high signal-to-noise ratio. The absolute line center frequencies of the ^{200}Hg and ^{202}Hg bosonic isotopes were measured with a global uncertainty of 8 and 15 kHz (namely, 6.8×10^{-12} and 1.3×10^{-11}, in relative terms), respectively, the statistical and systematic components being significantly reduced as compared to past determinations. This remarkable result was achieved also thanks to an in-depth study of the ac Stark effect. Furthermore, we found the most accurate ^{200}Hg-^{202}Hg isotope shift ever obtained before, namely, 5 295 57 0±15_{stat}±8_{syst} kHz.
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