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Updated: Jun 24, 2025

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A π-extended β-diketiminate ligand via a templated Scholl approach
Lars Killian1, Martin Lutz2, Arnaud Thevenon1
1Organic Chemistry and Catalysis, Institute for Sustainable and Circular Chemistry, Faculty of Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands. a.a.thevenon-kozub@uu.nl.
Abstract:
We report a templated Scholl oxidation strategy for the preparation of the first β-diketiminate (BDI) ligands embedded within a 24-electron π-system backbone. The resulting benzo[f,g]tetracene BDI ligand was coordinated to a zinc centre and electrochemical studies showed the redox active nature of the ligand.
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