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Updated: Jun 24, 2025
Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Atroposelective N-N Axes Synthesis via Electrochemical Cobalt Catalysis
Yingjie Sun1, Taixin Yang1, Qiuling Wang1
1College of Chemistry, Pingyuan Laboratory, Zhengzhou University, Zhengzhou 450001, China.
Abstract:
Here, we disclosed an unprecedented cobalt electrocatalyzed atroposelective C-H activation and annulation for the efficient construction of diversely functionalized N-N axes in an undivided cell. A broad range of allene substrates and benzamides bearing different functionalities are compatible with generating axially chiral products with good yields and excellent enantioselectivities (up to 92% yield and 99% ee). A series of synthetic applications and control experiments were also performed, which further expanded the practicality of this strategy.
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