Related Experiment Video
Updated: Jun 24, 2025

Experimental Methods for Investigation of Shape Memory Based Elastocaloric Cooling Processes and Model Validation
Published on: May 2, 2016
Giant elastocaloric effect at low temperatures in TmVO4 and implications for cryogenic cooling
Mark P Zic1, Matthias S Ikeda2, Pierre Massat2
1Department of Physics, and Geballe Laboratory for Advanced Materials, Stanford University, Stanford, CA 94305.
Adiabatic decompression of paraquadrupolar materials like TmVO[Formula: see text] shows promise for cryogenic cooling. Rapidly oscillating strain reveals the material
Area of Science:
- Condensed Matter Physics
- Materials Science
Background:
- Adiabatic decompression of paraquadrupolar materials is a potential cryogenic cooling technology.
- TmVO[Formula: see text] exhibits a continuous phase transition to a ferroquadrupole-ordered state at 2.15 K.
- Crystal electric field degeneracy in Tm ions contributes significant entropy above the phase transition.
Purpose of the Study:
- To investigate the adiabatic elastocaloric response of single-crystal TmVO[Formula: see text].
- To experimentally determine the entropy landscape as a function of strain and temperature.
- To assess the suitability of TmVO[Formula: see text] for cryogenic cooling applications.
Main Methods:
- Utilized a dynamic technique involving rapid strain oscillation.
- Measured the adiabatic elastocaloric response of single-crystal TmVO[Formula: see text].
- Analyzed the entropy landscape influenced by strain and temperature.
Main Results:
- Experimentally obtained the entropy landscape of TmVO[Formula: see text] under dynamic strain.
- Confirmed the significant magnetoelastic coupling and its tunability via strain.
- Provided insights into the dynamic quadrupole strain susceptibility.
Conclusions:
- TmVO[Formula: see text] is suitable for cryogenic cooling applications.
- The study validates the potential of paraquadrupolar materials for advanced cooling technologies.
- Understanding dynamic quadrupole strain susceptibility is crucial for material optimization.
Related Concept Videos
Phase Transitions: Melting and Freezing
Effects of Temperature on Free Energy
Temperature and Thermal Equilibrium
The concept of temperature has evolved from the common concepts of hot and cold. The scientific definition of temperature explains more than just our sense of hot and cold. Temperature is operationally defined as the quantity measured with a thermometer. Furthermore, temperature is...
Constant Volume Calorimetry
Atomic Spectroscopy: Effects of Temperature
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature...
Thermodynamic Potentials

