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Related Concept Videos

Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride01:26

Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride

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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
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Types Of Superconductors01:28

Types Of Superconductors

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A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
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Superconductor01:24

Superconductor

1.1K
A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
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Acid Halides to Alcohols: LiAlH4 Reduction01:19

Acid Halides to Alcohols: LiAlH4 Reduction

2.7K
Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
2.7K
Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

4.8K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
4.8K
Electrophilic Addition to Alkynes: Halogenation02:38

Electrophilic Addition to Alkynes: Halogenation

8.2K
Introduction
Halogenation is another class of electrophilic addition reactions where a halogen molecule gets added across a π bond. In alkynes, the presence of two π bonds allows for the addition of two equivalents of halogens (bromine or chlorine). The addition of the first halogen molecule forms a trans-dihaloalkene as the major product and the cis isomer as the minor product. Subsequent addition of the second equivalent yields the tetrahalide.
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Related Experiment Video

Updated: Jun 23, 2025

Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
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Superconducting ternary hydrides: progress and challenges.

Wendi Zhao1,2, Xiaoli Huang2, Zihan Zhang2

  • 1Institute of High Pressure Physics, School of Physical Science and Technology, Ningbo University, Ningbo 315211, China.

National Science Review
|June 17, 2024
PubMed
Summary
This summary is machine-generated.

Researchers are exploring ternary hydrides to achieve room-temperature superconductivity at lower pressures. This review discusses factors influencing their stability and superconductivity, addressing current challenges and future opportunities.

Keywords:
conventional superconductivityelectron–phonon couplinghigh pressureternary hydrides

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Chemistry

Background:

  • High-temperature superconductors like H3S and LaH10, while promising, require extreme pressures.
  • Binary hydrides with high superconducting transition temperatures (Tc) are often unstable at lower pressures, limiting practical applications.

Purpose of the Study:

  • To review recent advancements in ternary hydrides for superconductivity.
  • To elucidate key factors governing the structural stability and superconductivity of ternary hydrides.
  • To identify current challenges and future research directions in the field.

Main Methods:

  • Literature review of theoretical and experimental studies on ternary hydrides.
  • Analysis of structural motifs, bonding characteristics, electronic structures, and electron-phonon coupling.
  • Discussion of factors influencing superconducting transition temperature (Tc).

Main Results:

  • Ternary hydrides show promise for achieving superconductivity at lower pressures compared to binary hydrides.
  • Understanding structural, electronic, and bonding properties is crucial for designing stable and high-Tc materials.
  • Significant progress has been made, but challenges remain in optimizing material synthesis and properties.

Conclusions:

  • Ternary hydrides represent a promising avenue for developing practical room-temperature superconductors.
  • Further research is needed to overcome current limitations and fully realize the potential of these materials.
  • Interdisciplinary approaches combining theory and experiment are essential for future breakthroughs.