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Updated: Jun 23, 2025
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Solid-phase Synthesis of [4.4] Spirocyclic Oximes
Published on: February 6, 2019
An Intramolecular-Lock Facilitates Planar Tricyclic Fused Energetic Compounds
Yubing Liu1,2, Xun Zhang1,2, Jie Li1,2
1School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
Abstract:
Exploiting novel fused cyclic frameworks through simple and efficient methods has provided a blueprint for developing advanced explosives. In this study, six new [5,6,5]-tricyclic fused energetic compounds (I-VI) were synthesized through an intramolecular cyclization strategy involving a C-NH2 directed cyclization reaction. The work not only boosts the development of fused cyclic energetic compounds but also highlights their potential applications as secondary or heat-resistant explosives.
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