Characterization of phosphate modified red mud-based composite materials and study on heavy metal adsorption

In this paper, Bayer red mud (RM) and lotus leaf powder (LL) were used as the main materials, and KH₂PO₄ was added to modify the material. Under the condition of high-temperature carbonization, RMLL was prepared and phosphate modified red mud matrix composite (PRMLL) was prepared based on KH₂PO₄ modification, which can effectively remove Pb²⁺ from water. The optimum preparation and application conditions were determined through orthogonal experiment: dosage 0.1g, ratio 1:1, and temperature 600 °C. The effects of pH, dosage, and initial concentration on the adsorption of Pb²⁺ were studied. The pseudo-first-order, pseudo-second-order, and Elovich kinetic models were fitted to the experimental data. It was found that RMLL and PRMLL were more consistent with the pseudo-second-order kinetic model and chemisorption. Langmuir, Freundlich, Timkin, and Dubinin-Radushkevich isothermal adsorption models were used to fit the experimental data. It was found that RMLL and PRMLL were more consistent with Langmuir model. In addition, the maximum adsorption capacity of RMLL and PRMLL was 188.1 mg/g and 213.4 mg/g, respectively. It is larger than the adsorption capacity of their monomers. Therefore, the use of RMLL and PRMLL as the removal of Pb²⁺ from water is a potential application material.