Related Experiment Video
Updated: Jun 22, 2025

The Effect of Charging and Discharging Lithium Iron Phosphate-graphite Cells at Different Temperatures on Degradation
Published on: July 18, 2018
Investigation of Fe-Ni Battery/Module for Grid Service Duty Cycles.
Nimat Shamim1, Edwin C Thomsen1, Alasdair J Crawford2
1Battery Materials & System Group, Pacific Northwest National Laboratory, Richland, WA 99352, USA.
Iron-nickel batteries show promise for grid energy storage, offering stable performance in frequency regulation and peak shaving. Optimal state of charge and maintenance are key for maximizing efficiency and durability in these applications.
Area of Science:
- Electrochemistry
- Energy Storage Systems
- Materials Science
Background:
- Iron-nickel (Fe-Ni) batteries offer durability but face adoption hurdles due to low efficiency and high maintenance costs.
- Grid energy storage demands reliable and efficient battery technologies for applications like frequency regulation and peak shaving.
Purpose of the Study:
- To evaluate the feasibility and performance of Fe-Ni batteries in grid energy storage applications.
- To assess the impact of state of charge (SOC) on Fe-Ni battery efficiency and cyclability for grid services.
Main Methods:
- Frequency regulation (FR) testing at various states of charge (100%, 50%, 25%).
- Peak shaving (PS) testing under diverse load conditions.
- Extended cycling tests to evaluate long-term stability and reliability.
Main Results:
- Stable performance observed during FR testing at 100% and 50% SOC, with a 14% efficiency increase at 50% SOC compared to 100% SOC.
- Higher efficiency at 25% SOC was noted, but limited cyclability was observed due to discharge cutoff voltage.
- Fe-Ni batteries demonstrated stable results in PS testing and potential for long-term grid-scale applications through extended cycling.
Conclusions:
- Optimal SOC selection, battery monitoring, maintenance, and charging strategies are critical for effective FR applications of Fe-Ni batteries.
- Fe-Ni batteries show suitability and reliability for peak shaving applications.
- The study confirms the potential of Fe-Ni batteries for long-term grid-scale energy storage, particularly for FR and PS services.
More Related Videos
09:49A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery
Published on: February 13, 2017
11:25Identification and Quantification of Decomposition Mechanisms in Lithium-Ion Batteries; Input to Heat Flow Simulation for Modeling Thermal Runaway
Published on: March 7, 2022
Related Concept Videos
Batteries and Fuel Cells
DC Battery