Pt₃Sn_0.5Mn_0.5 Intermetallic Electrocatalyst with Superior Stability for CO-Resilient Methanol Oxidation

The sluggish kinetics of methanol oxidation reaction (MOR) and poor long-term durability of catalysts are the main restrictions of the large-scale applications of direct methanol fuel cells (DMFCs). Herein, we demonstrated an inspirational ternary Pt₃Sn_0.5Mn_0.5/DMC intermetallic catalyst that reached 4.78 mA cm^-2 and 2.39 A mg^-1_Pt for methanol oxidation, which were 2.50/2.44 and 5.62/5.31 times that of commercial PtRu/C and Pt/C. After the durability test, Pt₃Sn_0.5Mn_0.5/DMC presented a very low current density attenuation (38.5%), which was significantly lower than those for commercial PtRu/C catalyst (84.2%) and Pt/C (93.1%). Density functional theory (DFT) calculations revealed that the coregulation of Sn and Mn altered the surface electronic structure and endowed Pt₃Sn_0.5Mn_0.5 with selective adsorption of Pt for CO and Sn for OH, which optimized the adsorption strength for intermediates and improved the reaction kinetics of MOR. Beyond offering an advanced electrocatalyst, this study provided a new point of view for the rational design of superior methanol oxidation catalysts for DMFC.