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Related Concept Videos

Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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Updated: Jun 22, 2025

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Nature-Inspired Strategy: Novel Borohydride-Based Solid Electrolytes Extracted from Cathode-Electrolyte Interphase.

Yuhang Yin1, Fei Yan2, Shuyang Li1

  • 1Department of Materials Science, Fudan University, Shanghai, 200433, P. R. China.

Advanced Materials (Deerfield Beach, Fla.)
|June 29, 2024
PubMed
Summary

Researchers developed novel solid electrolytes derived from the cathode-electrolyte interphase (CEI) for advanced all-solid-state batteries. These new materials offer improved performance and compatibility, paving the way for next-generation energy storage solutions.

Keywords:
all‐solid‐batteriescathode‐electrolyte interphaselithium borohydridesnature‐inspiredsolid electrolytes

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Battery Technology

Background:

  • Solid-state electrolytes are crucial for all-solid-state batteries but face challenges in performance and interface compatibility.
  • Current electrolytes struggle to meet demands for high performance and stable interfaces with electrodes.

Purpose of the Study:

  • To propose a novel strategy for synthesizing solid electrolytes with comprehensive performance.
  • To develop electrolytes derived from the cathode-electrolyte interphase (CEI) for improved battery applications.

Main Methods:

  • A novel strategy was employed to synthesize solid electrolytes extracted from the cathode-electrolyte interphase (CEI).
  • Proof-of-concept studies utilized LiBH4-Se and LiBH4-S as prototype electrolytes.

Main Results:

  • As-synthesized electrolytes inherited and improved upon the advantages of LiBH4.
  • The novel electrolytes demonstrated unexpected compatibility with multiple cathode materials.
  • The CEI-derived electrolytes show promise for enhancing all-solid-state battery performance.

Conclusions:

  • A new class of solid electrolytes derived from CEI has been successfully synthesized.
  • This CEI-derived concept offers a fresh perspective for developing novel solid electrolytes.
  • The family of these new electrolytes is expected to expand, advancing battery technology.