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Updated: Jun 22, 2025
From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Crystal clear: unveiling giant birefringence in organic-inorganic cocrystals
1Department of Chemistry, Sogang University Seoul 04107 Republic of Korea kmok@sogang.ac.kr.
Abstract:
Coplanar groups with large anisotropic polarizability are suitable as birefringence-active groups for investigating compounds with significant birefringence. In this study, the organic coplanar raw reagent, o-C5H5NO (4HP), was selected as an individual complement. Utilizing the cocrystal engineering strategy, we successfully designed two cocrystals: [LiNO3·H2O·4HP]·4HP (Li-4HP2) and [Mg(NO3)2·6H2O]·(4HP)2 (Mg-4HP), and one by-product: LiNO3·H2O·4HP (Li-4HP), which were grown using a mild aqua-solution method. The synergy of the coplanar groups of NO3 - and 4HP in the structures resulted in unexpectedly large birefringence values of 0.376-0.522@546 nm. Furthermore, the compounds exhibit large bandgaps (4.08-4.51 eV), short UV cutoff edges (275-278 nm), and favorable growth habits, suggesting their potential as short-wave UV birefringent materials.
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