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Tuning the electronic properties of Zr UiO-66 through defect-functionalised multivariate modulation
Carmen Rosales-Martínez1, Marcelo Assis2, Celia Castillo-Blas3
1Instituto de Ciencia Molecular, Universitat de Valencia, Calle catedrático José Beltrán Martínez, 46980, Paterna, Valencia, Spain. isabel.abanades@uv.es.
Abstract:
The multivariate modulation of Metal-Organic Frameworks is presented as a valuable tool to introduce multiple functional units into UiO-66 while increasing its porosity. This manuscript encloses a comprehensive study using p-functionalised benzoate -NO2, -SO3 and -SH modulators, rationalizing the defects introduced and their impact on properties.
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