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Updated: Jun 20, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Rhodium(I) Complexes with a η1-Fluorenyl-P-phosphanylphosphorane Ligand
Javier Eusamio1,2, Nil Saumell1, Anton Vidal-Ferran1,2,3
1Departament de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Universitat de Barcelona, Martí i Franquès 1-11, E-08028 Barcelona, Spain.
Abstract:
The first example of a P-phosphanylphosphorane, Flu═PCy2-PCy2 (L2; Flu = 9-fluorenyl), has been easily prepared by P-phosphination of lithiated 9-dicyclohexylphosphinofluorene (FluPCy2, L0) with chlorodicyclohexylphosphane. L2 constitutes a new type of P(III)-P(V) organophosphorus compound, a σ3λ3-σ4λ5 species that is stable under an inert atmosphere in the solid state. The reaction of L2 with [Rh(diene)2]BR4 causes metalation of the benzylic carbon (C9) of fluorene, giving κ2-C,P complexes in which fluorene is coordinated in the η1 form. A complex with the weakly coordinating BArF anion has been isolated and fully characterized, including its crystal structure obtained by X-ray diffraction.
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