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Two-Dimensional MXene-Based Electrocatalysts: Challenges and Opportunities.

Muhammad Kaleem Shabbir1,2, Fozia Arif1,3, Haleema Asghar3

  • 1Functional nanomaterials Lab (FNL), Department of Chemistry Mirpur, University of Science and Technology (MUST), -10250 (AJK), Mirpur, Pakistan.

Chemical Record (New York, N.Y.)
|July 23, 2024
PubMed
Summary
This summary is machine-generated.

Two-dimensional (2D) MXene materials show great promise for electrocatalysis due to their unique properties. This review details MXene-based electrocatalyst design for various reactions and future research directions.

Keywords:
MXeneelectrocatalysthydrogen evolution reactionsnitrogen reduction reactionsoxygen evolution reactions

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Nanotechnology

Background:

  • Two-dimensional (2D) MXene materials are advanced materials with excellent flexibility, surface area, mechanical strength, and electrical conductivity.
  • MXenes are emerging as ideal platforms for designing highly active, selective, and stable electrocatalysts.
  • Electrocatalysis is crucial for energy conversion and storage technologies.

Purpose of the Study:

  • To provide a comprehensive review of structural engineering strategies for MXene-based electrocatalysts.
  • To summarize the applications of 2D MXenes in key electrochemical reactions, including hydrogen evolution, nitrogen reduction, oxygen evolution, oxygen reduction, and alcohol oxidation.
  • To discuss current challenges and future prospects for MXene electrocatalysts in fundamental research and practical applications.

Main Methods:

  • Literature review and synthesis of existing research on MXene-based electrocatalysts.
  • Analysis of structural engineering techniques applied to MXenes for enhanced catalytic performance.
  • Discussion of material design and enhancement strategies.

Main Results:

  • MXenes exhibit tunable properties through structural engineering, leading to improved electrocatalytic activity, selectivity, and stability.
  • MXene-based electrocatalysts have demonstrated significant potential in hydrogen evolution reactions (HER), nitrogen reduction reactions (NRR), oxygen evolution reactions (OER), oxygen reduction reactions (ORR), and methanol/ethanol oxidation.
  • Key challenges include controlling MXene structure, ensuring long-term stability, and scaling up production.

Conclusions:

  • MXenes represent a next-generation platform for advanced electrocatalyst development.
  • Further research into material design and enhancement techniques is crucial for optimizing MXene-based electrocatalyst efficiency.
  • Future directions include exploring novel MXene compositions and heterostructures for targeted electrocatalytic applications.