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Updated: Jun 18, 2025
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Published on: March 9, 2017
Advancing Molecular-Scale Logic Devices through Multistage Switching in a Luminescent Bimetallic Ru(II)-Terpyridine
Soumi Das1, Anik Sahoo1, Sujoy Baitalik1
1Inorganic Chemistry Section, Department of Chemistry, Jadavpur University, Kolkata 700032, India.
Abstract:
Stimuli-responsive multistep switching phenomena of a luminescent bimetallic Ru(II) complex are employed herein to fabricate multiple configurable logic devices. The complex exhibits "off-on" and "on-off" emission switching upon alternative treatment with visible and UV light. Additionally, remarkable augmentation of the rate as well as quantum yield of photoisomerization was achieved via the use of a chemical oxidant (Ce4+) as well as a reductant (metallic sodium). Upon exploiting the emission spectral response of the complex, several advanced Boolean logic functions, including IMPLICATION as well as 2-input 2-output and 3-input 2-output complex combinational logic gates, are successfully implemented. Additionally, by utilizing the vast efficacy of Python, a novel "logic_circuit" model is devised that is capable of making accurate decisions under the influence of various input combinations. This model transcends traditional Boolean logic gates, offering flexibility and intuition to design logical functions tailored to specific chemical contexts. By integrating principles of logic circuits with chemical processes, this innovative approach enables structure determination of the chemical states based on input conditions, thereby unlocking avenues for exploring intricate interactions and reactions beyond conventional Boolean logic paradigms.
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