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When the quality of water for concrete preparation is uncertain, its impact on the setting time of cement and compressive strength of mortar is assessed by comparison with de-ionized or distilled water benchmarks. American Society for Testing and Materials (ASTM) C1602 requires the setting times to be within 90 minutes of the control, British Standard (BS) 3146:1980 allows a 30-minute variance in the initial setting, while British Standards European Norm (BS EN) 1008 specifies initial setting...

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Defect-Engineered WO3- Architectures Coupled with Random Forest Algorithm Enables Real-Time Seafood Quality

Ziqi Zhang1, Junxuan Liang1, Kai Liu1

  • 1State Key Laboratory of Bio-Fibers and Eco-Textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, P. R. China.

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Summary

Engineered tungsten oxide (WO2.91) sensors detect triethylamine (TEA) for seafood quality. Defect engineering enhances sensor performance, enabling accurate prediction of fish spoilage.

Keywords:
defect-engineeringgas sensorsseafood qualitytriethylaminetungsten oxide

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Area of Science:

  • Materials Science
  • Chemical Sensing
  • Food Science

Background:

  • Accurate, real-time monitoring of seafood decay is crucial for food safety.
  • Identifying specific spoilage markers like triethylamine (TEA) in complex gas mixtures remains challenging.

Purpose of the Study:

  • To develop advanced triethylamine (TEA) sensors for seafood quality assessment.
  • To investigate the impact of defect engineering on tungsten oxide (WO3-x) gas sensing properties.

Main Methods:

  • Fabrication of defect-engineered WO3-x architectures, specifically WO2.91.
  • Characterization of sensor performance, including response, detection limit, selectivity, and stability.
  • Testing the sensor's ability to detect TEA during halibut decay.
  • Application of a random forest algorithm for predicting storage time.

Main Results:

  • The WO2.91 sensor demonstrated significantly enhanced TEA-sensing performance compared to WO2.96.
  • Key improvements included a 1.9-fold higher response, 2.1-fold faster response time, 3.2-fold lower detection limit, and 2.8-fold higher TEA/NH3 selectivity.
  • The sensor showed long-term stability and anti-interference capabilities.
  • Accurate prediction of halibut storage time (0-48 h) with 95% accuracy was achieved using the WO2.91 sensor and a random forest algorithm.

Conclusions:

  • Defect engineering in WO3-x is an effective strategy to enhance gas-sensing performance.
  • The developed WO2.91 sensor provides a reliable solution for real-time seafood quality assessment.
  • This approach offers valuable insights for designing improved gas sensors for various applications.