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Updated: Jun 17, 2025

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A Lead-μ2-Tetrylide Complex with Osmium(IV) Terminal Components
Javier A Cabeza1, Miguel A Esteruelas2, Israel Fernández3
1Departamento de Química Orgánica e Inorgánica, Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad de Oviedo, 33071 Oviedo, Spain.
Abstract:
A bare lead atom is a σ-donor ligand capable of linearly bonding and stabilizing two units of a classical polyhydride complex, with a high-valent metal center. As a proof of concept, we have prepared and characterized the μ2-tetrylide complex (PiPr3)2H4Os═Pb═OsH4(PiPr3)2 in the reaction of OsH6(PiPr3)2 with Pb{N(SiMe3)2}2. Although the Pb-Os bonds exhibit electrostatic interaction, the main orbital interactions result from two dative σ bonds from the lead atom to the osmium centers. The latter also provide much weaker π-backdonations.
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