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Updated: Jun 17, 2025
Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Structural, optical and magnetic properties of a new metal-organic CoII-based complex
Wiem Jabeur1, Marcus Korb2, Mohamed Hamdi3
1Laboratory Physico Chemistry of the Solid State, Department of Chemistry, Faculty of Sciences of Sfax, Sfax University POBOX 1171 3000 Sfax Tunisia houcine_naili@yahoo.com.
Abstract:
A mononuclear cobalt(ii) complex [C5H8N3]2[CoCl4(C5H7N3)2] (I) was synthesized and structurally characterized. Single crystal X-ray diffraction analysis indicates that monometallic Co(ii) ions acted as coordination nodes in a distorted octahedral geometry, giving rise to a supramolecular architecture. The latter is made up of a ½ unit form composed of an anionic element [Co0.5Cl2(C5H7N3)]- and one 2-amino-4-methylpyrimidinium cation [C5H8N3]+. The crystalline arrangement of this compound adopts the sandwich form where inorganic parts are sandwiched between the organic sheets following the [100] direction. More information regarding the structure hierarchy has been supplied based on Hirshfeld surface analysis; the X⋯H (X = N, Cl) interactions play a crucial role in stabilizing the self-assembly process of I, complemented by the intervention of π⋯π electrostatic interaction created between organic entities. Thermal analyses were carried out to study the thermal behavior process. Static magnetic measurements and ab initio calculations of compound I revealed the easy-axis anisotropy character of the central Co(ii) ion. Two-channel field-induced slow-magnetic relaxation was observed; the high-frequency channel is characterized by underbarrier relaxation with U eff = 16.5 cm-1, and the low-frequency channel involves a direct relaxation process affected by the phonon-bottleneck effect.
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