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Updated: Jun 15, 2025

Determination of Thermodynamic Properties of Alkaline Earth-liquid Metal Alloys Using the Electromotive Force Technique
Published on: November 3, 2017
Synthesis, characterization, and stability assessment of sodium and barium heptamolybdates
Andrés Lara-Contreras1, Mohammad Affan1, Gabrielle Schatte2
1Department of Chemistry and Chemical Engineering, Royal Military College of Canada, 13 General Crerar Crescent, Kingston, ON, K7K 7B4, Canada.
Abstract:
The study of complex phases in nuclear fuels is necessary to understand the physicochemical properties of the fuel. Na6Mo7O24⋅14H2O (1) was prepared via a simplified method and the crystal structure was improved. Upon thermal degradation, 1 decomposes into Na2Mo2O7 and MoO3. Additionally, novel Ba3Mo7O24⋅12H2O (2) was isolated via an aqueous synthetic route and characterized via FTIR and elemental analysis. PXRD pattern of 2 was determined. Thermal degradation of 2 indicates formation of BaMoO4, BaMo3O10, MoO3, and an unidentified phase.
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