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Electrospun carbon nanofibers loaded with sulfur vacancy CoS2 as separator coating to accelerate sulfur conversion in
Xinliang Men1, Teng Deng1, Xin Li1
1School of Mechanical and Electrical Engineering, Xi'an University of Architecture and Technology, Xi'an, Shaanxi 710311, China.
Abstract:
Lithium-sulfur batteries (LSBs) have been sought after by researchers owing to their high energy density; however, the inevitable capacity decay and slow reaction kinetics have hindered their advancement. Here, we prepare a Prussian blue analog, Co3[Co(CN)6]2 and synthesize carbon nanofibers/S vacancy CoS2-x (CNFs/CoS2-x) as electrocatalysts for separator coating via electrospinning, carbonization, sulfurization, and hydrogen reduction. CNFs/CoS2-x exhibits excellent electrocatalytic activity, wherein S vacancies induce the partial oxidation of Co2+ to Co3+ in CoS2 and CNFs provide long-range electron transport pathways. Various electrochemical tests, such as Tafel, ion diffusion coefficient, Li2S precipitation, and Li2S6 symmetric cells, further confirm the enhanced electrocatalytic activity. The LSBs with CNFs/CoS2-x modified separator delivers an initial discharge capacity of 1056.7 mAh g-1 at 0.2C, maintaining 840.8 mAh g-1 after 100 cycles at 0.2C. When S loading is increased to 4.42 mg cm-2, the battery retains a discharge capacity of 687.9 mAh g-1 (3.04 mAh cm-2) after 70 cycles at 0.1C. Our work can provide a reference for synthesizing anion-vacancy materials and designing anion-vacancy electrocatalytic composites for LSBs.
