Electrical nature of randomly oriented low-dimensional structural hybrids of carbon

Low-dimensional carbon materials are of great interest and have tremendous potential for application in flexible plastic electronics. However, the development of devices based on carbon structural hybrids is often hindered due to the high recombination rate of photoexcited charges, low absorbance, and other factors. This work discusses the emergence of multi-component structural forms of carbon from single-wall carbon nanotubes (SWCNTs) and demonstrates the electrical nature of the film containing these heterogeneous low-dimensional structural derivatives that are amalgamated in a polyurethane matrix. SWCNTs serve as a building block to give rise to multi-structural compounds, including multi-wall carbon nanotubes (MWCNTs), graphene sheets (GSs), carbon nanoscrolls (CNS), 'Y' and 'T' junctions, twisted CNTs and carbon nano-onion (CNO)-like structures, after performing oxidative purification and covalent functionalization processes. These one- and two-dimensional (1D and 2D) components with different individual electrical characteristics when integrated in a polyurethane binder and spin-coated on a SiO₂/Si substrate exhibit an overall semiconducting behaviour. Current (I)-voltage (V) characteristics reveal thermally driven photo-excited charges that are mainly responsible for the observed current trend of the film. Herein, we explore a facile cost-effective strategy to fabricate stable thin film coatings comprising a random network of functionalized structural derivatives of carbon and polymer conjugates and investigate the overall electrical nature to envisage incorporating these nanomaterials in future plastic electronics.