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Updated: Jun 14, 2025

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
Cylindrical HPIII-SbIII-Templated Five-Layer Polyoxotungstate with Conspicuous Photochromism Triggered by UV or
Miao Zhang1, Yunfan Zhang1, Lihua Liu1
1Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, China.
Abstract:
The heteroanion (HA) component plays an important role in the templating of heteropolyoxometalate (HPA) structures, but polyoxometalates (POMs) formed from two different templates are rarely reported. Herein, we present a five-layer POM [H2N(CH3)2]14{[(HPO3)4W6O10][HPSbW15O54]2}·16H2O (1) prepared by two kinds of different HA templates. The multilayer heteropolyanion {[(HPO3)4W6O10][HPSbW15O54]2}14- in 1 consists of two trivacant diheteroatom-templated ([HPO3]2- and [SbO3]3-) [HPSbW15O54]11- subunits linked by one unusual [(HPO3)4W6O10]8+ subcluster via twelve corner-sharing oxygen atoms. Compound 1 was systematically characterized by IR, UV, PXRD, TGA, XPS, and Raman spectra. Compound 1 exhibits good photochromism under UV irradiation with a half-life (t1/2) of 42.5 s, and it also exhibits noteworthy photochromism under visible light irradiation with a half-life (t1/2) of 157.2 s. The possible photochromic mechanism is proposed and verified by the experimental results.
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