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Updated: Jun 14, 2025

Fabrication Procedures and Birefringence Measurements for Designing Magnetically Responsive Lanthanide Ion Chelating Phospholipid Assemblies
Published on: January 3, 2018
Cl--templated coordination polymers constructed from dragonfly-like Ln4 clusters exhibiting excellent magnetothermal
Xu Bai1, Jian Wang1, Qin Wang1
1College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, P. R. China. yanxu@njtech.edu.cn.
Abstract:
Lanthanide clusters with high magnetic entropy and an exquisite structure have always been a hot research direction. Herein, two delicately structured lanthanide clusters were synthesized using isonicotinic acid (HIN) as a ligand by the solvothermal method, namely {[Gd4(IN)4(μ3-OH)4(OAc)2(H2O)6]·Cl2·7H2O} (1) and {[Dy4(IN)4(μ3-OH)4(OAc)2(H2O)6]·Cl2·8H2O} (2). Structural analysis indicates that the two compounds exhibit comparable structures, and both have the same cubane-like Ln4 metal skeleton and form an interesting dragonfly molecular configuration by connecting to HIN. Moreover, {Ln4} serves as the fundamental structural unit for the construction of a 1D channel of 1, with a diameter of approximately 10.08 Å, which is connected to each other by extra {Ln4} units to form an exquisite porous 3D structure of 1. Cl- exists as an anion-template in its 3D structure, balancing the charge and maintaining its structural stability. Magnetic measurements indicate that 1 exhibits a rather satisfactory magnetic entropy change, reaching a maximum value of -ΔSmaxm = 31.59 J kg-1 K-1 at 2 K for ΔH = 7 T.
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