Harnessing Enantioselective Optical Forces by Quasibound States in the Continuum

Enantioselective optical forces have garnered significant attention, because they provide a noninvasive means to separate chiral objects. A promising approach to enhance enantioselective optical forces is spatially overlapping and boosting electric and magnetic fields to create giant superchiral fields. Here, we utilize metasurfaces composed of asymmetric silicon dimers that support two distinct quasibound states in the continuum (quasi BICs). By precisely engineering these quasi BICs, we achieve nearly perfect spatial overlap of electric and magnetic fields near their anticrossing point, resulting in a remarkable 10^{4}-fold enhancement of the superchiral field. Consequently, the enantioselective optical force exerting on a single molecule exhibits a substantial increase, with magnitude up to pN/mW μm^{2}. Furthermore, by encircling the anticrossing point, we can switch the handedness of the superchiral field and the enantioselective optical force. Last, we analyze the dynamics of quasi-BIC-assisted chiral separation, highlighting its potential applications in chiral sensing and sorting, circular dichroism spectroscopy, and pharmacology.