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Magnetic Properties of High-Entropy Alloy FeCoNiTi
Jiro Kitagawa1, Daiki Shintaku1
1Department of Electrical Engineering, Faculty of Engineering, Fukuoka Institute of Technology, Fukuoka 811-0295, Japan.
Abstract:
We report the magnetic properties of the as-cast high-entropy alloy (HEA) FeCoNiTi, characterized by a dual phase comprising the face-centered cubic (fcc) and hexagonal C14 Laves phases. The HEA manifests three distinct ferromagnetic orderings at 1084, 214, and 168 K. The emergence of the 214 K transition is attributed to the influence of the C14 phase. The high-temperature ordering at 1084 K is associated with the fcc phase, which exhibits an additional ferromagnetic ordering at 168 K. The coercive field of the fcc phase attains 667 Oe at 400 K. Electronic structure calculations conducted for both phases substantiate the presence of ferromagnetic ground states. Comparative analyses between experimental and theoretical values are undertaken in the context of saturation magnetization. A comprehensive discussion is presented, delving into the origin of the relatively high coercive field observed at high temperatures in the fcc phase.
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