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NIR-triggered upconversion and sensitized NIR-emission in Yb-based Eosin Y lake doped latex nanoparticles
Rita B Cevallos-Toledo1, Delia Bellezza1, María González-Béjar1
1Instituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, Paterna, 46980 Valencia, Spain. julia.perez@uv.es.
Physical Chemistry Chemical Physics : PCCP
|September 9, 2024
Summary
Researchers developed photoactive Ytterbium-based Eosin Y (EOS-Yb) nanoparticles using microemulsion polymerization. These nanoparticles exhibit visible and near-infrared emission, along with upconversion capabilities for advanced optical applications.
Area of Science:
- Materials Science
- Nanotechnology
- Photochemistry
Background:
- Organic nanoparticles offer versatile platforms for incorporating photoactive materials.
- Ytterbium-based materials are known for their luminescent properties, including near-infrared emission and upconversion.
Purpose of the Study:
- To encapsulate Ytterbium-based Eosin Y (EOS-Yb) within organic nanoparticles (NPs).
- To investigate the photoluminescent properties of the resulting EOS-Yb NPs, including visible and near-infrared (NIR) emission and NIR-to-visible upconversion.
Main Methods:
- Microemulsion radical polymerization of methacrylate-based copolymers was employed for nanoparticle synthesis.
- Photoluminescence spectroscopy was used to characterize the emission properties upon excitation at 530 nm and 980 nm.
Main Results:
- Successfully synthesized photoactive EOS-Yb NPs via microemulsion polymerization.
- Demonstrated visible and NIR emission from EOS-Yb NPs upon 530 nm excitation.
- Observed NIR-to-visible upconversion emission upon 980 nm excitation.
Conclusions:
- Yb-based Eosin Y can be effectively encapsulated in organic nanoparticles.
- The developed EOS-Yb NPs possess dual-mode luminescence (emission and upconversion) for potential photonic applications.

