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Updated: Jun 13, 2025

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
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Steric Influences on Chain Microstructure in Palladium-Catalyzed α-Olefin (Co)polymerization: Unveiling the

Lihua Guo1, Jiaxing Li1, Wei Zhao1

  • 1Key Laboratory of Catalytic Conversion and Clean Energy in Universities of Shandong Province, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, P. R. China.

Inorganic Chemistry
|September 13, 2024
PubMed
Summary

This study reveals how palladium catalysts control polymer branching in chain walking polymerization. Bulky steric environments around palladium dramatically increase branching, creating high-melting-point polyethylene-like polymers.

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