Spectrometric monitoring of CO₂ electrolysis on a molecularly modified copper surface

Since copper has been extensively studied due to its unique ability to reduce carbon dioxide to hydrocarbons and alcohols, it tends to yield a mixture of products. Among various efforts to improve the selectivity and efficiency of this catalysis, the introduction of organic molecules and polymers on the copper/electrolyte interface has proven to be an effective and promising way to improve surface activity, considering the variation and precise designability of organic structures. The role of surface molecular modifiers, however, is not as simple as that in homogeneous catalysts, and an understanding of a wide scale of interactions from the atomic scale to the whole electrode structure is required. This feature article classifies those different scale interactions caused by organic modifiers on copper catalysts, together with the experimental support by in situ vibrational spectroscopy which directly observes surface species and events. Based on these recent understandings, novel fabrication methods of organic structures on copper catalysts are also discussed.