Photo-modified and photo-degradable starch/Fe₃O₄/TiO₂ nanocomposite: exploring the feasibility of reducing workforce...

Plastics are known for their durability and long decomposition time in the environment, which make plastic recycling an effective approach to mitigate plastic waste risks. However, the global plastic recycling rate is less than 10% mainly due to the labor-intensive and time-consuming nature of the manual recycling process, which poses high health risks and costs. Therefore, the development of a fast, effective, and operational process in current recycling plants is crucial to address the environmental concerns associated with plastics. In the current study, the feasibility of starch/Fe₃O₄/TiO₂ bio-nanocomposite (SFT) as photo-modifiable and photo-degradable was investigated to reduce the workforce in recycling packaging material. The SFT was modified by different UV-C exposure times, which significantly altered its functional properties. The UV-C exposure increased the hydrophobicity of the SFT films and led to a homogenous distribution of Fe₃O₄/TiO₂ nanoparticles (FT). It also increased tensile strength (TS) and decreased elongation at break (EB) of the films. It seems that producing shorter polymer chains, creating new linkages among the polymeric chains, and the homogenous distribution of FT in the matrix of biopolymer by UV-C are the main reasons for these changes. Moreover, the photo-degradation of SFT specimens increased significantly with longer UV-C exposure times. The utilization of magnetic properties in bio-based nanocomposites holds promising potential for streamlining labor-intensive processes in waste recycling plants. However, the inappropriate visual properties of SFT remain a significant obstacle that requires further attention to enable its commercial viability.