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Related Concept Videos

Trends in Lattice Energy: Ion Size and Charge02:54

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An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
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Updated: Jun 12, 2025

Focused Ion Beam Fabrication of LiPON-based Solid-state Lithium-ion Nanobatteries for In Situ Testing
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"Zero-Strain" NiNb2O6 Fibers for All-Climate Lithium Storage.

Yan Zhao1,2, Qiang Yuan2, Liting Yang3

  • 1College of Physics, Donghua University, Shanghai, 201620, People's Republic of China.

Nano-Micro Letters
|September 26, 2024
PubMed
Summary

Researchers developed "zero-strain" Nickel Niobate (NiNb2O6) fibers as advanced anode materials for lithium-ion batteries. These fibers offer excellent cyclability and performance across various temperatures, paving the way for durable, high-capacity batteries.

Keywords:
Operando characterizationElectrochemical propertyHarsh-temperature operationNiNb2O6 porous fiber“Zero-strain” mechanism

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Niobates show promise as lithium-ion (Li+) storage anode materials due to good charge transport and capacity.
  • A key limitation of niobates is moderate volume expansion during Li+ storage, hindering long-term battery cyclability.
  • Developing anode materials with improved volume stability is crucial for enhancing battery lifespan and performance.

Purpose of the Study:

  • To explore nickel niobate (NiNb2O6) fibers as a novel anode material for lithium-ion batteries.
  • To investigate the "zero-strain" behavior and electrochemical properties of NiNb2O6 fibers.
  • To assess the suitability of NiNb2O6 fibers for all-climate, high-performance lithium-ion battery applications.

Main Methods:

  • Synthesis and characterization of NiNb2O6 fibers.
  • Electrochemical testing of NiNb2O6 fibers as anode material in lithium-ion cells.
  • Analysis of volume changes and structural stability during lithium-ion (Li+) storage.

Main Results:

  • NiNb2O6 fibers exhibit "zero-strain" behavior during Li+ storage due to reversible oxygen movement, accommodating volume changes effectively.
  • The material demonstrates excellent long-term cyclability with high capacity retention (e.g., 92.8% after 1000 cycles at 10C and 25°C).
  • NiNb2O6 fibers show large reversible capacities (300 mAh g-1 at 0.1C, 25°C) and outstanding rate performance across a wide temperature range (-10°C to 60°C).

Conclusions:

  • NiNb2O6 fibers are a highly promising anode material for lithium-ion batteries, offering superior volume accommodation and electrochemical performance.
  • The "zero-strain" characteristic ensures excellent cyclability and stability in all-climate conditions.
  • These findings position NiNb2O6 fibers as ideal candidates for next-generation large-capacity, fast-charging, and long-life lithium-ion batteries.