Fine-Scale Aerosol-Jet Printing of Luminescent Metal-Organic Framework Nanosheets

Fabrication of metal-organic framework (MOF) thin films is an ongoing challenge to achieve effective device integration. Inkjet printing has been employed to print various luminescent metal-organic framework (MOF) films. Luminescent metal-organic nanosheets (LMONs), nanometer-thin particles of MOF materials with comparatively large micrometer lateral dimensions, provide an ideal morphology that offers enhancements over analogous MOFs in luminescent properties such as intensity and photoluminescent quantum yield. The morphology is also better suited to the formation of thin films. This work harnesses the preferential features of LMONs to access the advanced technique of aerosol-jet printing (AJP) to print luminescent films with precise geometries and patterns across the micrometer and centimeter length scales. AJP of LMONs exhibiting red (R), green (G), and blue (B) emission were studied systematically to reveal the increase of luminescence upon additive layering printing until a threshold was reached limited by self-quenching. By combining different LMON emitters, emission chromaticity and intensity were shown to be tunable, including the combination of RGB emitters to fabricate white-light-emitting films. A white-light LMON film was printed onto a UV light emitting diode (LED), producing a working white-light-emitting diode. Printing with multiple distinct photoluminescent inks produced intricate multicolor patterns that dynamically responded to excitation wavelength, acting either as micrometer-scale LED-type cells or larger visual tags. Collectively, the work offers an advancement for MOF thin films by printing MON materials using AJP, offering a precise method for manufacturing a wide range of critical functional devices, from luminescent sensors to optoelectronics, and more broadly even the opportunity for printed circuitry with conductive MONs.