S-Cu Doubly Doped NiFe LDH@Diatomite with Adjustable Surface Characteristics for the Efficient Removal of...

Overuse of antibiotics can lead to increased bacterial resistance; therefore, there is a need to develop efficient nanomaterials for removing antibiotics from water. NiFe bimetallic hydroxide nanosheets doped with S-Cu were prepared on diatomite (S-CuNiFe LDH@diatomite) by using a two-step hydrothermal method. The surface of CuNiFe LDH@DE has a layered structure with an increased specific surface area and pore volume. The average pore size of S-CuNiFe LDH@De increases from 13.3 to 24.7 nm, and a more stereoscopic channel structure is obtained. Tetracycline removal experiments were performed on CuNiFe LDH@De and S-CuNiFe LDH@De. It was found that CuNiFe LDH@De had excellent photocatalytic performance and S-CuNiFe LDH@De had excellent adsorption performance. After CuNiFe LDH@De had been in contact with tetracycline (TC) for 2 h, the TC removal rate reached 95.6%. After S-CuNiFe LDH@De had been in contact with TC for 1 h, the adsorption capacity of TC was 145.5 mg/g. The pseudo-first-order kinetics and Sips isotherm model can be used to describe the adsorption process more accurately. The response surface method was used to optimize the adsorption conditions. According to the optimized conditions, a better adsorption performance of 166.9 mg/g was obtained. The two prepared materials showed good performance in the removal of tetracycline. This study provides a way to synthesize low-cost adsorbents and photocatalysts, which has value in the treatment of TC wastewater.