Fabrication of Ag Nanoparticle-Embedded Covalent Organic Frameworks for Oil Gel with Long-Term Stability and High
Xiaozhi Zhang1, Yi Wang1, Tiantian Wang1
1State Key Laboratory of Solidification Processing, Center of Advanced Lubrication and Seal Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, PR China.
Abstract:
In previous reports, covalent organic frameworks (COFs) have demonstrated significant potential as lubricant additives. Herein, we embedded Ag nanoparticles in the DT-COF (polycondensation polymer of 2,5-dihydroxyterephthalaldehyde and 4,4',4″-(1,3,5-triazine-2,4,6-triyl) trianiline) matrix via the ball milling method and utilized this composite (Ag@DT-COF) as an additive for supermolecule oil gel. The low molecular weight gelator effectively mitigates the dispersion challenges of COFs in lubricant oil, while the embedded Ag nanoparticles enhance the repairing effect and antipressure performance of the lubricant. The resulting Ag@DT-COF gel exhibits a reduction in the average friction coefficient and wear volume of base oil by 46.0% and 87.5%, respectively, and increases the load-carrying capacity to 750 N. The remarkable tribological properties are attributed to the easy adsorption of DT-COF, antiwear characteristic of Ag nanoparticles, and the gelator that ensures the long-term stability of oil gel.
