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![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
A local hydroxyl group-modified copper site directs the oxidation of carbon monoxide
Guoqiang Cao1,2, Nan Yi1
1Department of Chemical Engineering and Bioengineering, University of New Hampshire, Durham, New Hampshire 03824, USA. nan.yi@unh.edu.
Abstract:
A washing step is employed to adjust the residual surface hydroxyl groups on the Cu-TiO2 catalysts, which in turn influences the local environment of copper species. Hydroxyl groups control both copper dispersion and the Cu+/Cu2+ ratio. Notably, a higher [Cu+]/[OH-] ratio is associated with an enhanced reaction rate in CO conversion.
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