Light-driven nitrogen fixation routes for green ammonia production

The global goal for decarbonization of the energy sector and the chemical industry could become a reality by a massive increase in renewable-based technologies. For this clean energy transition, the versatile green ammonia may play a key role in the future as a fossil-free fertilizer, long-term energy storage medium, chemical feedstock, and clean burning fuel for transportation and decentralized power generation. The high energy-intensive industrial ammonia production has triggered researchers to look for a step change in new synthetic approaches powered by renewable energies. This review provides a comprehensive comparison of light-mediated N₂ fixation technologies for green ammonia production, including photocatalytic, photoelectrocatalytic, PV-electrocatalytic and photothermocatalytic routes. Since these approaches are still at laboratory scale, we examine the most recent developments and discuss the open challenges for future improvements. Last, we offer a technoeconomic comparison of current and emerging ammonia production technologies, highlighting costs, barriers, recommendations, and potential opportunities for the real development of the next generation of green ammonia solutions.