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Updated: Jun 10, 2025

Preparation of Liquid-exfoliated Transition Metal Dichalcogenide Nanosheets with Controlled Size and Thickness: A State of the Art Protocol
Published on: December 20, 2016
Dimension-Dependent Nonlinear Optical Properties of Stanene Nanosheets
Yifan Huang1, Jingkun Wang2, Bowen Bai1
1Institute of Special Environment Physical Sciences, Harbin Institute of Technology, Shenzhen 518055, China.
Abstract:
Stanene (Sn)-based materials, with a graphene-like hexagonal structure, are now attracting considerable interest for potential applications in photoelectricity. However, the nonlinear optical properties of stanene remain largely unexplored. In this work, we prepared different sizes of stanene by liquid phase exfoliation and differential centrifugation methods, including two-dimensional (2D) Sn nanosheets (NSs) and zero-dimensional (0D) Sn nanodots (NDs). Z-scan measurements reveal that 2D Sn NSs exhibited high saturable absorption behavior, while the 0D Sn NDs led to reverse saturable absorption. Femtosecond ultrafast transient absorption spectra revealed that the reverse saturable absorption of Sn NDs is derived from a stronger excited state absorption and faster exciton relaxation dynamics. This research expands the potential applications of stanene in laser shielding and other ultrafast photonics technologies.
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