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Frozen Patterns in Viscoelastic Droplets Impacting on a Subcooled Surface.

Zhijun Jiang1, Wenyuan Zhong1, Youchuang Chao1

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Langmuir : the ACS Journal of Surfaces and Colloids
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Viscoelastic polymer droplet impact on cold surfaces shows reduced spreading with higher subcooling and polymer concentration. Unlike pure fluids, polymer droplets exhibit only two freezing modes: freezing and hierarchical cracking.

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Area of Science:

  • Fluid dynamics
  • Materials science
  • Surface science

Background:

  • Droplet impact on cold surfaces is crucial for aircraft icing and 3D printing.
  • Understanding complex fluid droplet dynamics on cold surfaces remains limited.

Purpose of the Study:

  • To experimentally investigate the impact, spreading, and freezing of viscoelastic polymer droplets on subcooled substrates.
  • To characterize the resulting frozen patterns and identify influencing parameters.

Main Methods:

  • Controlled droplet impact experiments using viscoelastic polymer solutions.
  • Varying subcooling temperatures and polymer concentrations.
  • Analysis of droplet spreading diameter and frozen pattern morphology.

Main Results:

  • Maximum droplet spreading diameter decreases with increasing subcooling and polymer concentration.
  • Spreading data collapses onto a universal curve governed by inertial, capillary, and viscous forces.
  • Polymer droplets exhibit two distinct freezing modes: freezing and hierarchical cracking, unlike pure fluids.

Conclusions:

  • A phase diagram was constructed to characterize frozen patterns based on undercooling and polymer concentration.
  • Findings offer insights into complex fluid solidification for applications like spray coating and additive manufacturing.