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Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
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Updated: Jul 3, 2026

Utilization of Plasmonic and Photonic Crystal Nanostructures for Enhanced Micro- and Nanoparticle Manipulation
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Development of a Photothermal Regenerative Plasmonic Platform as a Light-Controlled Interface.

Alexa Guglielmelli1, Rosalinda Mazzei2, Giovanna Palermo1

  • 1Nanoscience Laboratory for Human Technologies (NLHT) Lab, Department of Physics, Institute of Nanotechnology (CNR-Nanotec), University of Calabria, 87036 Rende, Italy.

ACS Applied Materials & Interfaces
|October 18, 2024
PubMed
Summary

This study presents a novel gold nanoparticle-embedded film for efficient photothermal conversion and pesticide degradation. The sustainable nanocomposite platform offers multifunctional applications and can be regenerated for repeated use.

Keywords:
biofunctionalizationbiosensorsgold nanoparticlesorganophosphate degradationphotothermal conversionplasmonic nanocompositespolydimethylsiloxane

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Environmental Science

Background:

  • Developing advanced materials for environmental remediation is crucial.
  • Photothermal conversion offers a promising route for targeted applications.
  • Enzyme immobilization within polymer matrices enables multifunctional platforms.

Purpose of the Study:

  • To develop a novel plasmonic nanocomposite platform for efficient photothermal conversion.
  • To create a biofunctionalized material for organophosphate pesticide degradation.
  • To demonstrate a sustainable and regenerable platform for multifunctional applications.

Main Methods:

  • In situ synthesis of gold nanoparticles (AuNPs) within a polydimethylsiloxane (PDMS) film.
  • Utilizing ethyl acetate swelling for uniform AuNP distribution without additional reagents.
  • Biofunctionalization of the nanocomposite with phosphotriesterase enzyme.

Main Results:

  • The nanocomposite film demonstrated exceptional photothermal conversion capabilities, rapidly reaching high temperatures upon light absorption.
  • The phosphotriesterase-functionalized platform effectively degraded organophosphate pesticides.
  • The platform exhibited regenerability, indicating suitability for repeated applications.

Conclusions:

  • A novel, sustainable plasmonic nanocomposite platform was successfully fabricated.
  • The platform shows significant potential for multifunctional applications in environmental remediation and beyond.
  • The in situ synthesis and biofunctionalization approach offers a versatile strategy for advanced material development.