Corrosion-resistant titanium-based electrodes synergistically stabilized with polymer for hydrogen evolution reaction

The economic and reasonable design of highly stable and corrosion-resistant electrodes is fundamental to achieving the industrial-scale hydrogen productions via water electrolysis, but electrodes' premature failures are often caused by corrosion and stress damage. Therefore, these challenges are successfully solved by utilizing conductive and crack-resistant polyaniline "stabilizer" with a mild chemical plating process to construct the catalytic electrode on a titanium substrate (15 %PANI-NiB@Ti) in the present work. The 15 %PANI-NiB@Ti catalytic electrodes have been in continuous operation for 350 h at the current density of 200 mA cm^-2 with the high efficiency of 98.4 % in a 323.15 K environment. With the high economy and universality, the catalytic electrodes have good catalytic performance and reliability in the extreme industrial environments, such as high temperature, air, and high current density. Except for the above advantages, the 15 %PANI-NiB@Ti catalytic electrodes also have good cracking resistance, which provides a novel and feasible approach to the industrial application of transition metal catalytic electrodes.