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Updated: Jun 9, 2025

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Published on: May 15, 2017
Evolution of the surface phase transitions in IrTe2
Govinda Kharal1, Bryan L Chavez1, Silu Huang1
1SmartState Center for Experimental Nanoscale Physics, Department of Physics and Astronomy, University of South Carolina, Columbia, SC, 29208, USA.
Investigating iridium ditelluride (IrTe2) phase transitions using second harmonic generation (SHG) reveals distinct symmetries. The study clarifies transition temperatures and symmetries, explaining literature variations and uncovering a low-temperature trigonal phase.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Solid State Chemistry
Background:
- Iridium ditelluride (IrTe2) exhibits complex phase transitions.
- The precise symmetry of each phase in IrTe2 remains debated in scientific literature.
Purpose of the Study:
- To investigate the temperature-dependent symmetry evolution of IrTe2.
- To clarify the phase transitions and associated symmetries using advanced optical techniques.
Main Methods:
- Second harmonic generation (SHG) measurements were performed across a wide temperature range (4-300 K).
- SHG polarimetry was employed to probe the material's symmetry properties.
Main Results:
- Two distinct transition temperatures (Ts1 and Ts2) were identified, explaining variations in reported data.
- Trigonal symmetry was confirmed above Ts1, triclinic symmetry between Ts1 and Ts2, and multiple stripe phases below Ts2.
- A reentrant trigonal phase with six-fold symmetry was observed below ~10 K.
Conclusions:
- The study elucidates the complex phase diagram of IrTe2 by precisely mapping its symmetries.
- The findings provide a unified explanation for previously conflicting experimental results.
- The low-temperature trigonal phase is highlighted as crucial for understanding observed phenomena.
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