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Updated: Jun 9, 2025

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
Published on: November 11, 2013
Engineering a high-capacity and long-cycle-life magnesium/lithium hybrid-ion battery using a lamellar SnSe2/SnSe/SnO2
Jiamin Liu1, Ting Zhou1, Yun Shen2
1Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241002, P. R. China. jyliu@iim.ac.cn.
Abstract:
Since the safety and costs of current lithium-ion batteries are non-ideal, engineering a new energy-storage systems is needed. Magnesium/lithium hybrid-ion batteries (MLHBs) combining fast kinetics of Li ions and a dendrite-free Mg anode are promising. Here, we describe our development of an MLHB using lamellar SnSe2/SnSe/SnO2 as cathode material and an all-phenyl complex (APC)-based electrolyte. The multi-layered cathode material generated from a hierarchical precursor is conducive to diffusion of Li+ and Mg2+ ions, and buffers volumetric changes efficiently. After 2000 cycles at 1.0 A g-1, the battery shows a specific capacity of 233 mA h g-1 and a Coulombic efficiency of 100%. It also shows excellent rate performances. These findings suggest that the cathode design working with optimized electrolyte will find many applications for high-performance energy-storage systems.

