Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration01:16

IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration

1.2K
A covalently bonded heteronuclear diatomic molecule can be modeled as two vibrating masses connected by a spring. The vibrational frequency of the bond can be expressed using an equation derived from Hooke's law, which describes how the force applied to stretch or compress a spring is proportional to the displacement of the spring. In this case, the atoms behave like masses, and the bond acts like a spring.
According to Hooke's law, the vibrational frequency is directly proportional to...
1.2K
¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

1.7K
The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene...
1.7K
Noncovalent Attractions in Biomolecules02:35

Noncovalent Attractions in Biomolecules

17.4K
17.4K
Van der Waals Interactions01:24

Van der Waals Interactions

63.6K
Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.
63.6K
Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)01:22

Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)

1.0K
Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
The extent of coupling depends on the C‑C bond length, the two H‑C‑C angles, any electron-withdrawing substituents, and the dihedral angle between the...
1.0K
Intermolecular Forces03:13

Intermolecular Forces

57.7K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
57.7K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Molecular Mode Selective Diels-Alder Cycloreversion under Vibrational Strong Coupling.

The journal of physical chemistry letters·2026
Same author

Altering Glass Transition in Polymer Films through Vibrational Strong Coupling.

The journal of physical chemistry letters·2025
Same author

Exploring superconductivity under strong coupling with the vacuum electromagnetic field.

The Journal of chemical physics·2025
Same author

Developments and Challenges Involving Triplet Transfer across Organic/Inorganic Heterojunctions for Singlet Fission and Photon Upconversion.

The journal of physical chemistry letters·2023
Same author

pH Jumps in a Protic Ionic Liquid Proceed by Vehicular Proton Transport.

The journal of physical chemistry letters·2022
Same author

Effects of the Structure and Temperature on the Nature of Excitons in the Mo<sub>0.6</sub>W<sub>0.4</sub>S<sub>2</sub> Alloy.

The journal of physical chemistry. C, Nanomaterials and interfaces·2022
Same journal

Stabilizing Pd Catalysts on Pentacoordinated Al<sup>3+</sup> Sites of Alumina for Efficient Hydrogenation of Hexafluoropropylene.

ChemPlusChem·2026
Same journal

Design, Synthesis, and Performance Characterization of BODIPY-Based NIR Probes for Aβ<sub>42</sub> Aggregate Detection.

ChemPlusChem·2026
Same journal

Eliminate the Metal Ion in the Edible Oil Based on High Extraction pH-Switchable Deep Eutectic Solvents.

ChemPlusChem·2026
Same journal

Cinoplatin: An Efficient Platinum(IV) Prodrug Effective in Inhibiting the Growth of Cervical Cancer.

ChemPlusChem·2026
Same journal

A Mitochondria-Targeted Flavokawain A Derivative Suppresses Lymphoma by Disrupting Oxidative Phosphorylation.

ChemPlusChem·2026
Same journal

CALPUCK: An Open Python Tool for Cremer-Pople Ring Puckering Analysis Including a New 2D Mapping of Seven-Membered Rings.

ChemPlusChem·2026
See all related articles

Related Experiment Video

Updated: Jun 9, 2025

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid
08:54

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid

Published on: January 25, 2020

5.6K

Impacting Non-Covalent Interactions through Vibrational Strong Coupling.

Sourav Maiti1, Gnana Maheswar Kothapalli1, Kalaivanan Nagarajan1

  • 1Department of Chemical Sciences, Tata Institute of Fundamental Research (TIFR), Homi Bhabha Road, Mumbai, 400005, India.

Chempluschem
|October 30, 2024
PubMed
Summary
This summary is machine-generated.

Vibrational Strong Coupling (VSC) alters material properties by creating hybrid light-matter states, even without light. This phenomenon influences non-bonding interactions like hydrogen bonds and pi-pi interactions.

Keywords:
Light-matter interactionNon-bonding interactionPolaritonic chemistryVibrational strong couplingVibro-polaritonic states

More Related Videos

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
08:22

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization

Published on: August 6, 2018

6.8K
Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy
10:37

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy

Published on: March 16, 2020

9.6K

Related Experiment Videos

Last Updated: Jun 9, 2025

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid
08:54

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid

Published on: January 25, 2020

5.6K
Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
08:22

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization

Published on: August 6, 2018

6.8K
Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy
10:37

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy

Published on: March 16, 2020

9.6K

Area of Science:

  • Quantum Chemistry
  • Materials Science
  • Physical Chemistry

Background:

  • Light-matter strong coupling, particularly Vibrational Strong Coupling (VSC), is a key research area.
  • VSC can modify material properties by creating hybrid states, even in the absence of external light.
  • These hybrid states, known as vibro-polaritons, form on the molecular energy ladder.

Purpose of the Study:

  • To review the observed effects of VSC on non-bonding interactions.
  • To explore the potential of vibro-polaritonic chemistry in molecular sciences.
  • To examine how VSC influences interactions governed by dispersive forces.

Main Methods:

  • Review of existing literature on Vibrational Strong Coupling.
  • Analysis of theoretical proposals regarding vibro-polaritonic states.
  • Examination of experimental observations of VSC's impact on molecular interactions.

Main Results:

  • VSC influences non-bonding interactions, including hydrogen bonding and π-π interactions.
  • The formation of vibro-polaritonic states is proposed to alter material properties.
  • Potential modifications include changes in polarity, polarizability, and Van der Waals forces.

Conclusions:

  • Vibro-polaritonic chemistry is an emerging field with significant potential.
  • VSC offers a novel pathway to tune material properties and chemical reactivity.
  • Further exploration is needed to fully understand the mechanisms and applications of VSC.