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Updated: Jun 7, 2025

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Recent developments in difunctionalization of unsaturated hydrocarbons with organosilicon reagents
Jiawei Mao1,2, Ming Chen1, Yao Zhong2
1College of Bioengineering, Dalian Polytechnic University, Dalian 116034, China. chenming@dlpu.edu.cn.
Abstract:
Organosilicon compounds have attracted considerable attention because of their special biological activities. Direct difunctionalization of unsaturated hydrocarbons with organosilicon reagents for the efficient construction of synthetically valuable silicon-functionalized compounds are featured with a high step and atom economy, which could form carbon-silicon/carbon-carbon bonds or carbon-silicon/carbon-hetero bonds in one step. This review summarizes the recent advances on this topic based on different unsaturated hydrocarbons along with typical examples and mechanisms.
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