Molecular Imprinting Strategy Enables Circularly Polarized Luminescence Enhancement of Recyclable Chiral Polymer
Nianwei Wang1, Ran Hong2, Gong Zhang1,3
1State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. China.
Abstract:
Circularly polarized luminescence (CPL) plays a crucial role in the fields of optical display and information technology. The pursuit of high dissymmetry factors (glum) and fluorescence quantum yields in CPL materials remains challenging due to inherent trade-offs. In this work, molecular imprinting technology is employed to develop novel CPL-active polymer films based entirely on achiral fluorene-based polymers, achieving an enhanced glum value exceeding 4.2 × 10-2 alongside high quantum yields. These chiral molecularly imprinted polymer films (MIPF) are synthesized via a systematic three-step process: co-assembly with limonene and a porphyrin derivative (TBPP), interchain crosslinking, and subsequent removal of small molecules. During this process, limonene acts as the chiral inducer, while TBPP serves dual roles as both the chiral enhancer and imprinted molecule. The elimination of TBPP creates chiral sites for various fluorescent molecules, facilitating full-color CPL emission. The chiral MIPF exhibits stable CPL performance even after multiple cycles of post-assembly and removal. Furthermore, these films can function as interfacial microreactors, enabling in situ chemical reactions that dynamically regulate CPL signals. Additionally, chiral self-organization within achiral azobenzene polymer films can also be achieved using MIPF, serving as intense chiral light sources.
