Related Experiment Video

Updated: Feb 17, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives

Published on: February 7, 2017

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Chirality Evolution in Supramolecular Polymers: Homochiral Aggregation and Temperature-Dependent Chirality Reversal.

Haotian Ma1, Zixiang He2, Qingping Song3

  • 1State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou Industrial Park, Suzhou 215123, China.

ACS Polymers Au
|February 16, 2026
PubMed
Summary

Chiral triarylamine tris-amide (TATA) monomers exhibit homochiral aggregation and temperature-induced chirality reversal in supramolecular polymers. This study elucidates the mechanisms behind these intriguing chirality anomalies.

Keywords:
chirality reversalhomochiral aggregationmonosignate Cotton effectsupramolecular chiral assemblytemperature dependent

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