Modular synthesis and facile network formation of catechol functionalized triblock copolymers
Fahed Albreiki1, Tobias Göckler1,2, Samanvaya Srivastava1,3,4,5
1Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, Los Angeles, CA 90095, USA. samsri@ucla.edu.
Abstract:
We report the synthesis of catechol-functionalized symmetric triblock polymers comprising densely functionalized catechol endblocks using anionic ring-opening polymerization (AROP) and thiol-ene click chemistry. The simplicity and modularity of our approach rely on a two-step synthesis that eliminates the need for catechol protection and enables the functionalization of precisely synthesized precursor polymers with catechol-containing thiols. Partial oxidation of the catechols on the triblock polymers to quinones enabled rapid gelation (within seconds) while retaining strong adhesive attributes.
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