Efficient green InP-based QD-LED by controlling electron injection and leakage

Green indium phosphide (InP)-based quantum dot light-emitting diodes (QD-LEDs) still suffer from low efficiency and short operational lifetime, posing a critical challenge to fully cadmium-free QD-LED displays and lighting^1-3. Unfortunately, the factors that underlie these limitations remain unclear and, therefore, no clear device-engineering guidelines are available. Here, by using electrically excited transient absorption spectroscopy, we find that the low efficiency of state-of-the-art green cadmium-free QD-LEDs (which ubiquitously adopt the InP-ZnSeS-ZnS core-shell-shell structure) originates from the ZnSeS interlayer because it imposes a high injection barrier that limits the electron concentration and trap saturation. We demonstrate, both experimentally and theoretically, that replacing the currently widely used ZnSeS interlayer with a thickened ZnSe interlayer enables improved electron injection and depressed leakage simultaneously, allowing to achieve a peak external quantum efficiency of 26.68% and T₉₅ lifetime (time for the luminance to drop to 95% of the initial value) of 1,241 h at an initial brightness of 1,000 cd m^-2 in green InP-based QD-LEDs emitting at 543 nm-exceeding the previous best values by a factor of 1.6 and 165, respectively^3,4.