Multi-scaled regulation for cholesteric organization of cellulose nanocrystals based on internal and external factors

Cellulose nanocrystals (CNCs), as one of the most promising bio-sourced materials, have been drawing increasing attention as they offer an attractive route for the rational design and sustainable manufacturing of photonic materials owing to their cholesteric self-assembly from the suspension to solid state. Such an organization process can be readily regulated depending on either internal factors or external forces. In this review, recent advances in the control over the self-assembly process and photonic organizations of CNCs are summarized. Furthermore, an in-depth understanding of diverse factors affecting the nano-scaled periodicity and micro-scaled alignment of CNC cholesteric organization is obtained from perspectives of bulk building blocks, solution environment, extra additives, and external forces. Additionally, the roles of the multi-sized photonic architecture associated with photonic-photonic coupling and the macrogeometry related to the complex confined self-assembly are highlighted for sophisticated CNC optical materials. Finally, insights into the future challenges in the field of CNC photonic materials, regarding the precise mechanism of CNC self-assembly and translation of CNC photonic technology from academia to industry, are proposed.