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Updated: Jun 6, 2025
![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Visible-Light-Induced Copper-Catalyzed Radical Reactions of Diazo Arylidene Succinimides to Access the Pyromellitic
Kajal B Meher1, Debasish Laha1, Pankaj D Dharpure1
1Department of Chemistry, Indian Institute of Science Education and Research (IISER)-Pune, Dr. Homi Bhabha Road, Pashan, 411008 Pune, Maharashtra, India.
Abstract:
The synthesis of pyromellitic diimides (PMDIs) through visible-light-promoted copper-catalyzed reaction of diazo arylidene succinimides has been accomplished without the use of external oxidants. This transformation involves a carbon radical from diazo arylidene succinimides with a copper catalyst or photocatalyst via the proton-coupled electron transfer (PCET) process. This approach successfully challenges a long-standing paradigm in the synthesis of PMDIs. Notably, copper complex (CuNCS) formed in situ proved to be playing a pivotal role to drive the reaction via photoinitiation. Additionally, we synthesized a PMDI molecule known for its prominent aggregation-induced emission (AIE) property. For the very first time, we have synthesized unsymmetrical PMDIs by employing the developed protocol.
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